Production of different morphologies and size of metallic W particles through hydrogen reduction

Production of different morphologies and size of metallic W particles through hydrogen reduction

Blog Article

In Enhanced Perception for Autonomous Vehicles at Obstructed Intersections: An Implementation of Vehicle to Infrastructure (V2I) Collaboration this investigation, the Li2CO3-assisted hydrogen reduction method was proposed to produce different morphologies and size of metallic tungsten particles.The effects of temperature and content of Li2CO3 additive were both considered.The experimental results showed that both the temperature and additive had great effects on the morphology and size of produced tungsten particles.As the increases of temperature and fraction of Li2CO3, the morphology of tungsten particles was changed from spherical to polyhedral; while the size of these particles was increased; and the obtained products became more and more dispersed.

The addition of Li2CO3 also affected the reduction rate dramatically.It was found that the Li2CO3 additive retarded the initial reduction reaction, but it could obviously improve the later reduction (WO2 to W) at a high temperature, furthermore, the higher fraction of Li2CO3 made this promotion more remarkable.Based on above results, the reduction mechanism was proposed: without ACP-GCN: The Identification of Anticancer Peptides Based on Graph Convolution Networks additive, the reduction entirely obeys pseudomorphic transformation mechanism at low temperature, and obeys CVT mechanism at high temperature; with additive, the reduction follows a mechanism of mixture of nucleation, pseudomorphic transformation and CVT at low temperature, while at high temperature, the sublimation of WO3, nucleation and CVT mechanisms all play important roles.Keywords: Li2CO3, Nucleation, Reduction, Morphology and size, Tungsten.